Enzymatic Spot Treatment SDS
Version number: GHS 1.0
SECTION 1: Identification
1.1 Product identifier
Relevant identified uses HS code
-
1.3 Details of the supplier of the safety data sheet
B&B Blending, LLC 10963 Leroy Drive Northglenn CO 80233 United States
Telephone: 1.800.875.6320, 1.303.289.6320 e-mail: info@bbblending.com
Website: bbblending.come-mail (competent person)
-
1.4 Emergency telephone number
Emergency information service
SECTION 2: Hazard(s) identification
2.1 Classification of the substance or mixture
Date of compilation: 2023-02-23
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Enzymatic Cleaner
Enzymatic Cleaner
1.2 Relevant identified uses of the substance or mixture and uses advised against
Trade name
Enzyme based cleaner Professional use Industrial use
3402.42.90 .
btirrell@bbblending.com
USA 1.800.535.5053, INTL 1.352.323.3500 24 hr emergency information
Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)
For full text of abbreviations: see SECTION 16.
2.2 Label elements
Labelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) - Signal word warning
- Pictograms
GHS07
- Hazard statements
H319 Causes serious eye irritation.
- Precautionary statements
Section |
Hazard class |
Category |
Hazard class and category |
Hazard state- ment |
A.3 |
serious eye damage/eye irritation |
2 |
Eye Irrit. 2 |
H319 |
P280 P305+P351+P338
P337+P313 United States: en
Wear protective gloves/protective clothing/eye protection/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Page: 1 / 12
Version number: GHS 1.0
2.3 Other hazards
Date of compilation: 2023-02-23
Hazards not otherwise classified
Harmful to aquatic life (GHS category 3: aquatic toxicity - acute).
Results of PBT and vPvB assessment
Does not contain a PBT-/vPvB-substance in a concentration of ≥ 0,1%.
Endocrine disrupting properties
Does not contain an endocrine disruptor (EDC) in a concentration of ≥ 0,1%.
SECTION 3: Composition/information on ingredients
-
3.1 Substances
Not relevant (mixture)
-
3.2 Mixtures
Description of the mixture
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Enzymatic Cleaner
Hazardous ingredients acc. to GHS |
||||
Name of substance |
Identifier |
Wt% |
Classification acc. to GHS |
Notes |
multi-bacillus spore blend pro- ducing lipase / protease / amylase / cellulase / urease |
5 – < 12 |
Acute Tox. 4 / H302 Skin Irrit. 2 / H315 Eye Irrit. 2 / H319 |
||
Alcohols, C9-11 ethoxylated |
CAS No 68439-46-3 |
1 – < 3 |
Acute Tox. 4 / H302 Acute Tox. 4 / H312 Eye Dam. 1 / H318 HNOC005 |
For full text of abbreviations: see SECTION 16. Exact percentage of ingredients is withheld as a trade secret.
This table, if present, includes all GHS classified ingredients present above their cut-off limits, even if the finished product is not classified as hazardous by GHS.
SECTION 4: First-aid measures
4.1 Description of first-aid measures
General notes
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give anything by mouth.
Following inhalation
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. Provide fresh air.
Following skin contact
Wash with plenty of soap and water.
Following eye contact
Remove contact lenses, if present and easy to do. Continue rinsing.
Following ingestion
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.
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Version number: GHS 1.0
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Date of compilation: 2023-02-23
Suitable extinguishing media
Water spray, BC-powder, Carbon dioxide (CO2)
-
5.2 Special hazards arising from the substance or mixture
-
5.3 Advice for firefighters
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Enzymatic Cleaner
In case of fire and/or explosion do not breathe fumes. Coordinate firefighting measures to the fire surroundings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water separately. Fight fire with normal pre- cautions from a reasonable distance.
SECTION 6: Accidental release measures
-
6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel Remove persons to safety.
For emergency responders
Wear breathing apparatus if exposed to vapors/dust/aerosols/gases. -
6.2 Environmental precautions
-
6.3 Methods and material for containment and cleaning up
Advice on how to contain a spill Covering of drains
Advice on how to clean up a spill
Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage: sawdust, kieselgur (diatomite), sand, universal binderAppropriate containment techniques Use of adsorbent materials.
Other information relating to spills and releases
Place in appropriate containers for disposal. Ventilate affected area. -
6.4 Reference to other sections
Personal protective equipment: see section 8. Incompatible materials: see section 10. Disposal considerations: see section 13.
SECTION 7: Handling and storage
-
7.1 Precautions for safe handling
Recommendations
- Measures to prevent fire as well as aerosol and dust generation Use local and general ventilation. Use only in well-ventilated areas.
Advice on general occupational hygiene
Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment be- fore entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs.
-
7.2 Conditions for safe storage, including any incompatibilities
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Version number: GHS 1.0
Control of the effects
Date of compilation: 2023-02-23
Protect against external exposure, such as frost
7.3 Specific end use(s)
See section 16 for a general overview.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limit values (Workplace Exposure Limits) this information is not available
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Enzymatic Cleaner
Relevant DNELs of components of the mixture |
||||||
Name of sub- stance |
CAS No |
End- point |
Threshold level |
Protection goal, route of expos- ure |
Used in |
Exposure time |
Alcohols, C9-11 eth- oxylated |
68439-46-3 |
DNEL |
2,080 mg/ kg |
human, dermal |
worker (industry) |
chronic - systemic effects |
Alcohols, C9-11 eth- oxylated |
68439-46-3 |
DNEL |
294 mg/m3 |
human, inhalatory |
worker (industry) |
chronic - systemic effects |
Relevant PNECs of components of the mixture |
||||||
Name of sub- stance |
CAS No |
End- point |
Threshold level |
Organism |
Environmental compartment |
Exposure time |
Alcohols, C9-11 eth- oxylated |
68439-46-3 |
PNEC |
0.1 mg/l |
aquatic organisms |
freshwater |
short-term (single instance) |
Alcohols, C9-11 eth- oxylated |
68439-46-3 |
PNEC |
0.1 mg/l |
aquatic organisms |
marine water |
short-term (single instance) |
Alcohols, C9-11 eth- oxylated |
68439-46-3 |
PNEC |
1.4 mg/l |
microorganisms |
sewage treatment plant (STP) |
short-term (single instance) |
Alcohols, C9-11 eth- oxylated |
68439-46-3 |
PNEC |
14 mg/kg |
benthic organisms |
sediment |
short-term (single instance) |
Alcohols, C9-11 eth- oxylated |
68439-46-3 |
PNEC |
14 mg/kg |
pelagic organisms |
sediment |
short-term (single instance) |
Alcohols, C9-11 eth- oxylated |
68439-46-3 |
PNEC |
1 mg/kg |
terrestrial organ- isms |
soil |
short-term (single instance) |
Alcohols, C9-11 eth- oxylated |
68439-46-3 |
PNEC |
0.014 mg/l |
aquatic organisms |
water |
intermittent release |
8.2 Exposure controls
Appropriate engineering controls General ventilation.
Individual protection measures (personal protective equipment)
Eye/face protection Wear eye/face protection.
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Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Enzymatic Cleaner
Version number: GHS 1.0
Skin protection
- Hand protection
Date of compilation: 2023-02-23
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/im- permeability prior to use. In the case of wanting to use the gloves again, clean them before taking off and air them well. For spe- cial purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.
- Other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended. Wash hands thoroughly after handling.
Environmental exposure controls
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties Appearance
Other safety parameters
Physical state |
liquid |
Color |
white |
Particle |
not relevant (liquid) |
Odor |
fresh |
pH (value) |
6 – 8 (25 °C) |
Melting point/freezing point |
not determined |
Initial boiling point and boiling range |
100 °C |
Flash point |
not determined |
Evaporation rate |
Not determined |
Flammability (solid, gas) |
not relevant, (fluid) |
Vapor pressure |
32 hPa at 25 °C |
Density |
0.99 – 1 g/cm3 |
Vapor density |
this information is not available |
Solubility(ies) |
not determined |
Partition coefficient
- n-octanol/water (log KOW) |
this information is not available |
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Version number: GHS 1.0
9.2 Other information
SECTION 10: Stability and reactivity
10.1 Reactivity
Date of compilation: 2023-02-23
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Enzymatic Cleaner
Auto-ignition temperature |
311 °C |
Viscosity |
not determined |
Explosive properties |
none |
Oxidizing properties |
none |
Temperature class (USA, acc. to NEC 500) |
T2 (maximum permissible surface temperature on the equipment: 300°C) |
Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials".
-
10.2 Chemical stability
See below "Conditions to avoid".
-
10.3 Possibility of hazardous reactions
No known hazardous reactions.
-
10.4 Conditions to avoid
There are no specific conditions known which have to be avoided.
-
10.5 Incompatible materials
There is no additional information.
-
10.6 Hazardous decomposition products
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are not known. Hazardous combustion products: see section 5.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Test data are not available for the complete mixture.
Classification procedure
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).
Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)
Acute toxicity
Shall not be classified as acutely toxic.
Acute toxicity estimate (ATE) of components of the mixture |
|||
Name of substance |
CAS No |
Exposure route |
ATE |
multi-bacillus spore blend producing lipase / pro- tease / amylase / cellulase / urease |
oral |
570 mg/kg |
|
Alcohols, C9-11 ethoxylated |
68439-46-3 |
oral |
1,200 mg/kg |
Alcohols, C9-11 ethoxylated |
68439-46-3 |
dermal |
2,000 mg/kg |
United States: en
Page: 6 / 12
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Enzymatic Cleaner
Version number: GHS 1.0
Date of compilation: 2023-02-23
Skin corrosion/irritation
Shall not be classified as corrosive/irritant to skin.
Serious eye damage/eye irritation Causes serious eye irritation.
Respiratory or skin sensitization
Shall not be classified as a respiratory or skin sensitizer.
Germ cell mutagenicity
Shall not be classified as germ cell mutagenic.
Carcinogenicity
Shall not be classified as carcinogenic.
Reproductive toxicity
Shall not be classified as a reproductive toxicant.
Specific target organ toxicity - single exposure
Shall not be classified as a specific target organ toxicant (single exposure).
Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.
SECTION 12: Ecological information
12.1 Toxicity
Harmful to aquatic life.
Aquatic toxicity (acute) of components of the mixture |
|||||
Name of substance |
CAS No |
Endpoint |
Value |
Species |
Exposure time |
Alcohols, C9-11 eth- oxylated |
68439-46-3 |
LC50 |
8.5 mg/l |
fathead minnow |
96 h |
Alcohols, C9-11 eth- oxylated |
68439-46-3 |
EC50 |
5.3 mg/l |
daphnia magna |
48 h |
Alcohols, C9-11 eth- oxylated |
68439-46-3 |
ErC50 |
1 – 10 mg/l |
algae |
96 h |
-
12.2 Persistence and degradability
Data are not available.
-
12.3 Bioaccumulative potential
Data are not available.
-
12.4 Mobility in soil
Data are not available.
-
12.5 Results of PBT and vPvB assessment
According to the results of its assessment, this substance is not a PBT or a vPvB. Does not contain a PBT-/vPvB-substance in a concentration of ≥ 0,1%.
United States: en Page: 7 / 12
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Enzymatic Cleaner
Version number: GHS 1.0
12.6 Endocrine disrupting properties
Date of compilation: 2023-02-23
Does not contain an endocrine disruptor (EDC) in a concentration of ≥ 0,1%.
12.7 Other adverse effects
Data are not available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Sewage disposal-relevant information
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.
Waste treatment of containers/packages
Completely emptied packages can be recycled. Handle contaminated packages in the same way as the substance itself.
Remarks
Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled separately by the local or national waste management facilities.
SECTION 14: Transport information
-
14.1 UN number
-
14.2 UN proper shipping name
-
14.3 Transport hazard class(es)
-
14.4 Packing group
-
14.5 Environmental hazards
-
14.6 Special precautions for user
There is no additional information.
-
14.7 Transport in bulk according to IMO instruments
The cargo is not intended to be carried in bulk.
Information for each of the UN Model Regulations
Transport of dangerous goods by road or rail (49 CFR US DOT)Not subject to transport regulations.
International Maritime Dangerous Goods Code (IMDG)
Not subject to IMDG.
International Civil Aviation Organization (ICAO-IATA/DGR)
Not subject to ICAO-IATA.
not subject to transport regulations not relevant
none
not assigned
non-environmentally hazardous acc. to the dangerous goods regulations
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Version number: GHS 1.0
SECTION 15: Regulatory information
Date of compilation: 2023-02-23
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Enzymatic Cleaner
15.1 Safety, health and environmental regulations specific for the product in question National regulations (United States)
Toxic Substance Control Act (TSCA) all ingredients are listed Superfund Amendment and Reauthorization Act (SARA TITLE III )
- The List of Extremely Hazardous Substances and Their Threshold Planning Quantities (EPCRA Section 302, 304)
none of the ingredients are listed
- Specific Toxic Chemical Listings (EPCRA Section 313) none of the ingredients are listed
Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA)
- List of Hazardous Substances and Reportable Quantities (CERCLA section 102a) (40 CFR 302.4) none of the ingredients are listed
Clean Air Act
none of the ingredients are listed
Right to Know Hazardous Substance List
- Cleaning Product Right to Know Act Substance List (CA-RTK)
Name of substance |
CAS No |
Functionality |
Authoritative Lists |
water |
7732-18-5 |
solvent |
|
multi-bacillus spore blend producing lipase / protease / amylase / cellulase / urease |
enzyme(s) |
||
Alcohols, C9-11 ethoxylated |
68439-46-3 |
surfactant |
|
sodium xylene sulphonate |
1300-72-7 |
surfactant |
|
1,1-dimethyl-2-phenylethyl acetate |
151-05-3 |
fragrance |
|
Dihydromyrcenol |
18479-58-8 |
fragrance |
|
gamma Undecalactone |
104-67-6 |
fragrance |
|
2-tert-Butylcyclohexyl acetate |
88-41-5 |
fragrance |
|
Butylated hydroxytoluene |
128-37-0 |
preservative |
|
beta-Ionone |
14901-07-6 |
fragrance |
|
Tricyclodecen-4-yl 8-acetate |
5413-60-5 |
fragrance |
|
Allyl heptanoate |
142-19-8 |
fragrance |
|
cyclamen aldehyde |
103-95-7 |
fragrance |
|
alpha-Terpineol acetate |
80-26-2 |
fragrance |
- Toxic or Hazardous Substance List (MA-TURA) none of the ingredients are listed
California Environmental Protection Agency (Cal/EPA): Proposition 65 - Safe Drinking Water and Toxic Enforcement Act of 1987
none of the ingredients are listed
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Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Enzymatic Cleaner
Version number: GHS 1.0
VOC content
Date of compilation: 2023-02-23
- Regulated Volatile Organic Compounds (VOC-EPA)
- Regulated Volatile Organic Compounds (VOC-Cal ARB)
Industry or sector specific available guidance(s)
NPCA-HMIS® III
Hazardous Materials Identification System. American Coatings Association.
0.16 % 0.16 %
Category |
Rating |
Description |
Chronic |
/ |
none |
Health |
2 |
temporary or minor injury may occur |
Flammability |
0 |
material that will not burn under typical fire conditions |
Physical hazard |
0 |
material that is normally stable, even under fire conditions, and will not react with water, polymerize, decompose, condense, or self-react. Non-explosive |
Personal protection |
- |
Chronic: Flammability: Health:
Personal protection: Physical hazard:
NFPA® 704
chronic hazard
flammability hazards
health hazard
personal protective equipment (PPE) for normal use reactivity
National Fire Protection Association: Standard System for the Identification of the Hazards of Materials for Emergency Re- sponse (United States).
Category |
Degree of hazard |
Description |
Flammability |
1 |
material that must be preheated before ignition can occur |
Health |
0 |
material that, under emergency conditions, would offer no hazard beyond that of ordinary combustible material |
Instability |
0 |
material that is normally stable, even under fire conditions |
Special hazard |
National inventories
Country |
Inventory |
Status |
CA |
DSL |
not all ingredients are listed |
EU |
REACH Reg. |
not all ingredients are listed |
US |
TSCA |
all ingredients are listed as "ACTIVE" |
AU |
AIIC |
not all ingredients are listed |
CN |
IECSC |
not all ingredients are listed |
EU |
ECSI |
not all ingredients are listed |
JP |
CSCL-ENCS |
not all ingredients are listed |
JP |
ISHA-ENCS |
not all ingredients are listed |
KR |
KECI |
not all ingredients are listed |
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Version number: GHS 1.0
Legend
AIIC
CICR CSCL-ENCS DSL
ECSI
IECSC INSQ ISHA-ENCS KECI
NZIoC PICCS REACH Reg. TCSI
TSCA
Date of compilation: 2023-02-23
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Enzymatic Cleaner
Country |
Inventory |
Status |
MX |
INSQ |
not all ingredients are listed |
NZ |
NZIoC |
not all ingredients are listed |
PH |
PICCS |
not all ingredients are listed |
TR |
CICR |
not all ingredients are listed |
TW |
TCSI |
not all ingredients are listed |
Australian Inventory of Industrial Chemicals
Chemical Inventory and Control Regulation
List of Existing and New Chemical Substances (CSCL-ENCS)
Domestic Substances List (DSL)
EC Substance Inventory (EINECS, ELINCS, NLP)
Inventory of Existing Chemical Substances Produced or Imported in China National Inventory of Chemical Substances
Inventory of Existing and New Chemical Substances (ISHA-ENCS)
Korea Existing Chemicals Inventory
New Zealand Inventory of Chemicals
Philippine Inventory of Chemicals and Chemical Substances (PICCS) REACH registered substances
Taiwan Chemical Substance Inventory
Toxic Substance Control Act
15.2 Chemical Safety Assessment
Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information, including date of preparation or last revision
Indication of changes (revised safety data sheet)
Alignment to regulation: Globally Harmonized System of Classification and Labelling of Chemicals ("Purple book"). Restructuring: section 9, section 14
Abbreviations and acronyms
Abbr. |
Descriptions of used abbreviations |
49 CFR US DOT |
49 CFR U.S. Department of Transportation |
Acute Tox. |
Acute toxicity |
ATE |
Acute Toxicity Estimate |
Cal ARB |
California Air Resources Board |
CAS |
Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances) |
DGR |
Dangerous Goods Regulations (see IATA/DGR) |
DNEL |
Derived No-Effect Level |
EC50 |
Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing 50 % changes in response (e.g. on growth) during a specified time interval |
EINECS |
European Inventory of Existing Commercial Chemical Substances |
ELINCS |
European List of Notified Chemical Substances |
EPA |
Environmental Protection Agency. An agency of the federal government of the United States charged with protect- ing human health and the environment |
ErC50 |
≡ EC50: in this method, that concentration of test substance which results in a 50 % reduction in either growth (EbC50) or growth rate (ErC50) relative to the control |
United States: en
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Version number: GHS 1.0
Date of compilation: 2023-02-23
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Enzymatic Cleaner
Abbr. |
Descriptions of used abbreviations |
Eye Dam. |
Seriously damaging to the eye |
Eye Irrit. |
Irritant to the eye |
GHS |
"Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations |
HS |
Harmonized Commodity Description and Coding System (Harmonized System, drawn up by the World Customs Organisation) |
IATA |
International Air Transport Association |
IATA/DGR |
Dangerous Goods Regulations (DGR) for the air transport (IATA) |
ICAO |
International Civil Aviation Organization |
IMDG |
International Maritime Dangerous Goods Code |
LC50 |
Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing 50 % lethal- ity during a specified time interval |
NLP |
No-Longer Polymer |
NPCA-HMIS® III |
National Paint and Coatings Association: Hazardous Materials Identification System - HMIS® III, Third Edition |
OSHA |
Occupational Safety and Health Administration (United States) |
PBT |
Persistent, Bioaccumulative and Toxic |
PNEC |
Predicted No-Effect Concentration |
Skin Corr. |
Corrosive to skin |
Skin Irrit. |
Irritant to skin |
VOC |
Volatile Organic Compounds |
vPvB |
Very Persistent and very Bioaccumulative |
Key literature references and sources for data
OSHA Hazard Communication Standard (HCS), 29 CFR 1910.1200.
Transport of dangerous goods by road or rail (49 CFR US DOT). International Maritime Dangerous Goods Code (IMDG). Dan- gerous Goods Regulations (DGR) for the air transport (IATA).
Classification procedure
Physical and chemical properties: The classification is based on tested mixture.
Health hazards, Environmental hazards: The method for classification of the mixture is based on ingredients of the mixture (ad- ditivity formula).
List of relevant phrases (code and full text as stated in section 2 and 3)
Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for this product.
Code |
Text |
H302 |
Harmful if swallowed. |
H312 |
Harmful in contact with skin. |
H315 |
Causes skin irritation. |
H318 |
Causes serious eye damage. |
H319 |
Causes serious eye irritation. |
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