Degreaser SDS

Version number: GHS 1.0

SECTION 1: Identification

1.1 Product identifier

Relevant identified uses

1.3 Details of the supplier of the safety data sheet

B&B Blending, LLC 10963 Leroy Drive Northglenn CO 80233 United States

Telephone: 1.800.875.6320, 1.303.289.6320 e-mail: info@bbblending.com
Website: bbblending.com

e-mail (competent person)
1.4 Emergency telephone number

Emergency information service

SECTION 2: Hazard(s) identification

2.1 Classification of the substance or mixture

Date of compilation: 2023-02-23

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

Degreaser
1.2 Relevant identified uses of the substance or mixture and uses advised against

Trade name

Cleaner/degreaser Professional use Industrial use

btirrell@bbblending.com

USA 1.800.535.5053, INTL 1.352.323.3500 24 hr emergency information

Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)

For full text of abbreviations: see SECTION 16.

The most important adverse physicochemical, human health and environmental effects The product is combustible and can be ignited by potential ignition sources.

2.2 Label elements

Labelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) - Signal word warning
- Pictograms

GHS07

Section	Hazard class	Category	Hazard class and category	Hazard state- ment
A.2	skin corrosion/irritation	2	Skin Irrit. 2	H315
A.3	serious eye damage/eye irritation	2	Eye Irrit. 2	H319
A.4S	skin sensitization	1	Skin Sens. 1	H317
B.6	flammable liquid	4	Flam. Liq. 4	H227

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Version number: GHS 1.0

- Hazard statements H227

H315 H317 H319

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

Combustible liquid.
Causes skin irritation.
May cause an allergic skin reaction. Causes serious eye irritation.

Date of compilation: 2023-02-23

- Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 If on skin: Wash with plenty of water.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and

easy to do. Continue rinsing.
P321 Specific treatment (see on this label).

P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention.

P362 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.

P370+P378 In case of fire: Use sand, carbon dioxide or powder extinguisher to extinguish.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

- Hazardous ingredients for labelling

2.3 Other hazards

This material is combustible, but will not ignite readily. Hazards not otherwise classified

Contains orange oil. May produce an allergic reaction.
Harmful to aquatic life (GHS category 3: aquatic toxicity - acute).

orange oil

Results of PBT and vPvB assessment
Does not contain a PBT-/vPvB-substance in a concentration of ≥ 0,1%.

Endocrine disrupting properties
Contains an endocrine disruptor (EDC) in a concentration of ≥ 0,1%.

SECTION 3: Composition/information on ingredients

3.1 Substances

Not relevant (mixture)
3.2 Mixtures

Description of the mixture

Hazardous ingredients acc. to GHS
Name of substance	Identifier	Wt%	Classification acc. to GHS	Notes
sodium dodecylbenzenesulf- onate	CAS No 25155-30-0	1 – < 20	Acute Tox. 4 / H302 Acute Tox. 2 / H330 Skin Irrit. 2 / H315 Eye Irrit. 2A / H319 HNOC002 HNOC006

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

Version number: GHS 1.0 Date of compilation: 2023-02-23

Hazardous ingredients acc. to GHS
Name of substance	Identifier	Wt%	Classification acc. to GHS	Notes
orange oil	CAS No 8028-48-6 68647-72-3	0.2 – < 10	Skin Irrit. 2 / H315 Skin Sens. 1 / H317 Asp. Tox. 1 / H304 Flam. Liq. 3 / H226 HNOC009
2-butoxy-1-ethanol	CAS No 111-76-2	1 – < 5	Acute Tox. 4 / H302 Acute Tox. 4 / H312 Acute Tox. 4 / H332 Skin Irrit. 2 / H315 Eye Irrit. 2 / H319 Flam. Liq. 4 / H227
sodium metasilicate, anhyd- rous	CAS No 6834-92-0	1.5 – < 2.1	Acute Tox. 4 / H302 Acute Tox. 3 / H331 Skin Corr. 1B / H314 STOT SE 3 / H335

For full text of abbreviations: see SECTION 16. Exact percentage of ingredients is withheld as a trade secret.

This table, if present, includes all GHS classified ingredients present above their cut-off limits, even if the finished product is not classified as hazardous by GHS.

SECTION 4: First-aid measures

4.1 Description of first-aid measures

General notes

Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give anything by mouth.

Following inhalation

If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case of respiratory tract ir- ritation, consult a physician. Provide fresh air.

Following skin contact
Wash with plenty of soap and water.

Following eye contact
Remove contact lenses, if present and easy to do. Continue rinsing.

Following ingestion
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media
Water spray, Alcohol resistant foam, BC-powder, Carbon dioxide (CO2)
5.2 Special hazards arising from the substance or mixture

In case of insufficient ventilation and/or in use, may form flammable/explosive vapor-air mixture. Solvent vapors are heavier than air and may spread along floors. Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammable substances or mixtures.

Hazardous combustion products
Carbon monoxide (CO), Carbon dioxide (CO2)

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Version number: GHS 1.0

5.3 Advice for firefighters

Date of compilation: 2023-02-23

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

In case of fire and/or explosion do not breathe fumes. Coordinate firefighting measures to the fire surroundings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water separately. Fight fire with normal pre- cautions from a reasonable distance.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel Remove persons to safety.

For emergency responders
Wear breathing apparatus if exposed to vapors/dust/aerosols/gases.
6.2 Environmental precautions
6.3 Methods and material for containment and cleaning up

Advice on how to contain a spill Covering of drains

Advice on how to clean up a spill
Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage: sawdust, kieselgur (diatomite), sand, universal binder

Appropriate containment techniques Use of adsorbent materials.

Other information relating to spills and releases
Place in appropriate containers for disposal. Ventilate affected area.
6.4 Reference to other sections

Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible materials: see sec- tion 10. Disposal considerations: see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Recommendations

- Measures to prevent fire as well as aerosol and dust generation

Use local and general ventilation. Avoidance of ignition sources. Keep away from sources of ignition - No smoking. Take pre- cautionary measures against static discharge. Use only in well-ventilated areas. Due to danger of explosion, prevent leakage of vapours into cellars, flues and ditches. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilat- ing/lighting/equipment. Use only non-sparking tools.

- Specific notes/details

Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are particu- larly prone to the presence of flammable substances or mixtures. Vapors are heavier than air, spread along floors and form ex- plosive mixtures with air. Vapors may form explosive mixtures with air.

- Handling of incompatible substances or mixtures Do not mix with acids.

Advice on general occupational hygiene

Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment be- fore entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs.

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Version number: GHS 1.0

Date of compilation: 2023-02-23

7.2 Conditions for safe storage, including any incompatibilities

Managing of associated risks

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

- Explosive atmospheres
Keep container tightly closed and in a well-ventilated place. Use local and general ventilation. Keep cool. Protect from sunlight.

- Flammability hazards

Keep away from sources of ignition - No smoking. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take precautionary measures against static discharge. Protect from sunlight.

Control of the effects

Protect against external exposure, such as frost

- Ventilation requirements
Use local and general ventilation. Ground/bond container and receiving equipment.

7.3 Specific end use(s)

See section 16 for a general overview.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limit values (Workplace Exposure Limits)
Coun try	Name of agent	CAS No	Iden- tifier	TWA [ppm]	TWA [mg/ m3]	STEL [ppm]	STEL [mg/ m3]	Ceil- ing-C [ppm]	Ceil- ing-C [mg/ m3]	Nota tion	Sourc e
US	2-butoxyethanol	111-76-2	REL	5 (10 h)	24 (10 h)						NIOS H REL
US	2-butoxyethanol	111-76-2	TLV®	20							AC- GIH® 2019
US	2-butoxyethanol	111-76-2	PEL	50	240						29 CFR 1910.1 000
US	2-butoxyethanol (EGBE) (glycol monobutyl ether)	111-76-2	PEL (CA)	20	97						Cal/ OSHA PEL

Notation

Ceiling-C STEL

TWA

ceiling value is a limit value above which exposure should not occur
short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period (unless otherwise specified)
time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-weighted average (unless otherwise specified

Biological limit values
Country	Name of agent	Parameter	Nota- tion	Identifier	Value	Source
US	2-butoxyethanol	Butoxyacetic acid (BAA)	hydr, crea	BEI®	200 mg/g	ACGIH® 2019

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Version number: GHS 1.0 Notation

Date of compilation: 2023-02-23

crea hydr

creatinine hydrolysis

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

Relevant DNELs of components of the mixture
Name of sub- stance	CAS No	End- point	Threshold level	Protection goal, route of expos- ure	Used in	Exposure time
2-butoxy-1-ethanol	111-76-2	DNEL	75 mg/kg	human, dermal	worker (industry)	chronic - systemic effects
2-butoxy-1-ethanol	111-76-2	DNEL	98 mg/m3	human, inhalatory	worker (industry)	chronic - systemic effects
2-butoxy-1-ethanol	111-76-2	DNEL	1,091 mg/ m3	human, inhalatory	worker (industry)	acute - systemic ef- fects
2-butoxy-1-ethanol	111-76-2	DNEL	246 mg/m3	human, inhalatory	worker (industry)	acute - local effects
sodium metasilicate, anhydrous	6834-92-0	DNEL	6.2 mg/m3	human, inhalatory	worker (industry)	chronic - systemic effects
sodium metasilicate, anhydrous	6834-92-0	DNEL	1.5 mg/kg bw/day	human, dermal	worker (industry)	chronic - systemic effects
sodium dodecylben- zenesulfonate	25155-30-0	DNEL	52 mg/m3	human, inhalatory	worker (industry)	chronic - systemic effects
sodium dodecylben- zenesulfonate	25155-30-0	DNEL	52 mg/m3	human, inhalatory	worker (industry)	acute - systemic ef- fects
sodium dodecylben- zenesulfonate	25155-30-0	DNEL	52 mg/m3	human, inhalatory	worker (industry)	chronic - local ef- fects
sodium dodecylben- zenesulfonate	25155-30-0	DNEL	52 mg/m3	human, inhalatory	worker (industry)	acute - local effects
sodium dodecylben- zenesulfonate	25155-30-0	DNEL	57 mg/kg bw/day	human, dermal	worker (industry)	chronic - systemic effects
sodium dodecylben- zenesulfonate	25155-30-0	DNEL	80 mg/kg bw/day	human, dermal	worker (industry)	acute - systemic ef- fects
orange oil	8028-48-6 68647-72-3	DNEL	31 mg/m3	human, inhalatory	worker (industry)	chronic - systemic effects
orange oil	8028-48-6 68647-72-3	DNEL	8.9 mg/kg bw/day	human, dermal	worker (industry)	chronic - systemic effects
orange oil	8028-48-6 68647-72-3	DNEL	186 μg/cm2	human, dermal	worker (industry)	acute - local effects

Relevant PNECs of components of the mixture
Name of sub- stance	CAS No	End- point	Threshold level	Organism	Environmental compartment	Exposure time
2-butoxy-1-ethanol	111-76-2	PNEC	463 mg/l	microorganisms	sewage treatment plant (STP)	short-term (single instance)
2-butoxy-1-ethanol	111-76-2	PNEC	35 mg/kg	benthic organisms	sediment	short-term (single instance)
2-butoxy-1-ethanol	111-76-2	PNEC	9.1 mg/l	aquatic organisms	water	intermittent release

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

Version number: GHS 1.0

Date of compilation: 2023-02-23

Relevant PNECs of components of the mixture
Name of sub- stance	CAS No	End- point	Threshold level	Organism	Environmental Exposure time compartment
2-butoxy-1-ethanol	111-76-2	PNEC	8.8 mg/l	aquatic organisms	freshwater short-term (single instance)
2-butoxy-1-ethanol	111-76-2	PNEC	0.88 mg/l	aquatic organisms	marine water short-term (single instance)
2-butoxy-1-ethanol	111-76-2	PNEC	463 mg/l	aquatic organisms	sewage treatment short-term (single plant (STP) instance)
2-butoxy-1-ethanol	111-76-2	PNEC	35 mg/kg	aquatic organisms	freshwater sediment short-term (single instance)
2-butoxy-1-ethanol	111-76-2	PNEC	3.5 mg/kg	aquatic organisms	marine sediment short-term (single instance)
2-butoxy-1-ethanol	111-76-2	PNEC	2.3 mg/kg	terrestrial organ- isms	soil short-term (single instance)
sodium dodecylben- zenesulfonate	25155-30-0	PNEC	0.69 mg/l	aquatic organisms	freshwater short-term (single instance)
sodium dodecylben- zenesulfonate	25155-30-0	PNEC	1 mg/l	aquatic organisms	marine water short-term (single instance)
sodium dodecylben- zenesulfonate	25155-30-0	PNEC	50 mg/l	aquatic organisms	sewage treatment short-term (single plant (STP) instance)
sodium dodecylben- zenesulfonate	25155-30-0	PNEC	28 mg/kg	aquatic organisms	freshwater sediment short-term (single instance)
sodium dodecylben- zenesulfonate	25155-30-0	PNEC	2.8 mg/kg	aquatic organisms	marine sediment short-term (single instance)
sodium dodecylben- zenesulfonate	25155-30-0	PNEC	25 mg/kg	terrestrial organ- isms	soil short-term (single instance)
orange oil	8028-48-6 68647-72-3	PNEC	2.1 mg/l	microorganisms	sewage treatment short-term (single plant (STP) instance)
orange oil	8028-48-6 68647-72-3	PNEC	1.3 mg/kg	benthic organisms	sediment short-term (single instance)
orange oil	8028-48-6 68647-72-3	PNEC	0.13 mg/kg	pelagic organisms	sediment short-term (single instance)
orange oil	8028-48-6 68647-72-3	PNEC	44 mg/kg	(top) predators	water short-term (single instance)
orange oil	8028-48-6 68647-72-3	PNEC	5.8 μg/l	aquatic organisms	water intermittent release
orange oil	8028-48-6 68647-72-3	PNEC	5.4 μg/l	aquatic organisms	freshwater short-term (single instance)
orange oil	8028-48-6 68647-72-3	PNEC	0.54 μg/l	aquatic organisms	marine water short-term (single instance)
orange oil	8028-48-6 68647-72-3	PNEC	2.1 mg/l	aquatic organisms	sewage treatment short-term (single plant (STP) instance)
orange oil	8028-48-6 68647-72-3	PNEC	1.3 mg/kg	aquatic organisms	freshwater sediment short-term (single instance)
orange oil	8028-48-6 68647-72-3	PNEC	0.13 mg/kg	aquatic organisms	marine sediment short-term (single instance)

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Individual protection measures (personal protective equipment)

Eye/face protection Wear eye/face protection.

Skin protection

- Hand protection

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

Version number: GHS 1.0

8.2 Exposure controls

Appropriate engineering controls General ventilation.

Date of compilation: 2023-02-23

Relevant PNECs of components of the mixture
Name of sub- stance	CAS No	End- point	Threshold level	Organism	Environmental compartment	Exposure time
orange oil	8028-48-6 68647-72-3	PNEC	0.26 mg/kg	terrestrial organ- isms	soil	short-term (single instance)

Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/im- permeability prior to use. In the case of wanting to use the gloves again, clean them before taking off and air them well. For spe- cial purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.

- Other protection measures

Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended. Wash hands thoroughly after handling.

Environmental exposure controls
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties Appearance

Other safety parameters

Physical state	liquid
Color	orange
Particle	not relevant (liquid)
Odor	citrus - creamsicle

pH (value)	12 – 12 (25 °C) (base)
Melting point/freezing point	not determined
Initial boiling point and boiling range	100 °C
Flash point	83 °C at 101 kPa 181 °F at 1 atm
Evaporation rate	Not determined

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

Version number: GHS 1.0

Solubility(ies)

Partition coefficient

Date of compilation: 2023-02-23

Flammability (solid, gas)	not relevant, (fluid)
Vapor pressure	32 hPa at 25 °C
Density	1 g/cm3 at 25 °C
Vapor density	this information is not available

- Water solubility

miscible in any proportion

- n-octanol/water (log KOW)	this information is not available
Auto-ignition temperature	230 °C (auto-ignition temperature (liquids and gases))
Viscosity	not determined
Explosive properties	none
Oxidizing properties	none

9.2 Other information

SECTION 10: Stability and reactivity

10.1 Reactivity

Dust explosion class	ST 0 (not dust explosion capable)
Temperature class (USA, acc. to NEC 500)	T2D (maximum permissible surface temperature on the equipment: 215°C)

Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials". The mixture contains reactive sub- stance(s). Risk of ignition.

If heated:
Risk of ignition

10.2 Chemical stability

See below "Conditions to avoid".
10.3 Possibility of hazardous reactions

No known hazardous reactions.
10.4 Conditions to avoid

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Hints to prevent fire or explosion

Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge.
10.5 Incompatible materials

Oxidizers

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Version number: GHS 1.0

Date of compilation: 2023-02-23

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

Release of flammable materials with:
Light metals (due to the release of hydrogen in an acid/alkaline medium)

10.6 Hazardous decomposition products

Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are not known. Hazardous combustion products: see section 5.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Test data are not available for the complete mixture.

Classification procedure
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).

Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)

Acute toxicity
Shall not be classified as acutely toxic.

Acute toxicity estimate (ATE) of components of the mixture
Name of substance	CAS No	Exposure route	ATE
2-butoxy-1-ethanol	111-76-2	oral	1,414 mg/kg
2-butoxy-1-ethanol	111-76-2	inhalation: vapor	11 mg/l/4h
sodium metasilicate, anhydrous	6834-92-0	oral	1,349 mg/kg
sodium metasilicate, anhydrous	6834-92-0	inhalation: vapor	>2.1 mg/l/4h
sodium metasilicate, anhydrous	6834-92-0	inhalation: dust/mist	0.5 mg/l/4h
sodium dodecylbenzenesulfonate	25155-30-0	oral	650 mg/kg
sodium dodecylbenzenesulfonate	25155-30-0	inhalation: dust/mist	0.31 mg/l/4h

Skin corrosion/irritation Causes skin irritation.

Serious eye damage/eye irritation Causes serious eye irritation.

Respiratory or skin sensitization May cause an allergic skin reaction.

Germ cell mutagenicity
Shall not be classified as germ cell mutagenic.

Carcinogenicity
Shall not be classified as carcinogenic.

Legend
3 Not classifiable as to carcinogenicity in humans

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans
Name of substance	CAS No	Classification	Remarks	Number
2-butoxy-1-ethanol	111-76-2	3

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

Specific target organ toxicity - single exposure
Shall not be classified as a specific target organ toxicant (single exposure).

Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).

Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

SECTION 12: Ecological information

12.1 Toxicity

Harmful to aquatic life.

Version number: GHS 1.0

Date of compilation: 2023-02-23

Reproductive toxicity
Shall not be classified as a reproductive toxicant.

Aquatic toxicity (acute) of components of the mixture
Name of substance	CAS No	Endpoint	Value	Species	Exposure time
2-butoxy-1-ethanol	111-76-2	LC50	1,474 mg/l	fish	96 h
2-butoxy-1-ethanol	111-76-2	EC50	1,550 mg/l	aquatic invertebrates	48 h
2-butoxy-1-ethanol	111-76-2	ErC50	1,840 mg/l	algae	72 h
sodium metasilicate, an- hydrous	6834-92-0	LC50	310 mg/l	fish	96 h
sodium metasilicate, an- hydrous	6834-92-0	EC50	1,700 mg/l	aquatic invertebrates	48 h
sodium dodecylben- zenesulfonate	25155-30-0	LC50	7.2 mg/l	fish	96 h
sodium dodecylben- zenesulfonate	25155-30-0	EC50	6.3 mg/l	aquatic invertebrates	48 h
sodium dodecylben- zenesulfonate	25155-30-0	ErC50	29 mg/l	algae	96 h
orange oil	8028-48-6 68647-72-3	LL50	5.7 mg/l	fish	96 h
orange oil	8028-48-6 68647-72-3	EL50	1.4 mg/l	aquatic invertebrates	24 h

12.2 Persistence and degradability

Data are not available.
12.3 Bioaccumulative potential

Data are not available.
12.4 Mobility in soil

Data are not available.
12.5 Results of PBT and vPvB assessment

According to the results of its assessment, this substance is not a PBT or a vPvB. Does not contain a PBT-/vPvB-substance in a concentration of ≥ 0,1%.

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

Version number: GHS 1.0

12.6 Endocrine disrupting properties

Date of compilation: 2023-02-23

Contains an endocrine disruptor (EDC) in a concentration of ≥ 0,1%.

12.7 Other adverse effects

Data are not available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Waste treatment-relevant information Solvent reclamation/regeneration.

Sewage disposal-relevant information
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.

Waste treatment of containers/packages
Completely emptied packages can be recycled. Handle contaminated packages in the same way as the substance itself.

Remarks

Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled separately by the local or national waste management facilities.

SECTION 14: Transport information

14.1 UN number
14.2 UN proper shipping name
14.3 Transport hazard class(es)
14.4 Packing group
14.5 Environmental hazards
14.6 Special precautions for user

There is no additional information.
14.7 Transport in bulk according to IMO instruments

The cargo is not intended to be carried in bulk.

Information for each of the UN Model Regulations
Transport of dangerous goods by road or rail (49 CFR US DOT)

Not subject to transport regulations.

International Maritime Dangerous Goods Code (IMDG)

Not subject to IMDG.

International Civil Aviation Organization (ICAO-IATA/DGR)

Not subject to ICAO-IATA.

not subject to transport regulations not relevant
none
not assigned

non-environmentally hazardous acc. to the dangerous goods regulations

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Version number: GHS 1.0

SECTION 15: Regulatory information

Date of compilation: 2023-02-23

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

15.1 Safety, health and environmental regulations specific for the product in question National regulations (United States)
Toxic Substance Control Act (TSCA) all ingredients are listed Superfund Amendment and Reauthorization Act (SARA TITLE III )

- The List of Extremely Hazardous Substances and Their Threshold Planning Quantities (EPCRA Section 302, 304)

none of the ingredients are listed

Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA)

- List of Hazardous Substances and Reportable Quantities (CERCLA section 102a) (40 CFR 302.4)

Legend
1 "1" indicates that the statutory source is section 311(b)(2) of the Clean Water Act

Clean Air Act

none of the ingredients are listed

Right to Know Hazardous Substance List

- Cleaning Product Right to Know Act Substance List (CA-RTK)

Name of substance	CAS No	Remarks	Statutory code	Final RQ pounds (Kg)
sodium dodecylbenzenesulfonate	25155-30-0		1	1000 (454)

Name of substance	CAS No	Functionality	Authoritative Lists
water	7732-18-5	solvent
2-butoxy-1-ethanol	111-76-2	co-solvent	OEHHA RELs
sodium metasilicate, anhydrous	6834-92-0	cleaning agent
sodium dodecylbenzenesulfonate	25155-30-0	surfactant
orange oil	8028-48-6 68647-72-3	fragrance
Isodecyloxypropyliminodipropionic acid, mono- sodium salt	64972-19-6	surfactant
isopropyl alcohol	67-63-0	alcohols	OEHHA RELs
EDTA, anhydrous	64-02-8	chelate / se- questrant
Alcohols, C9-11 ethoxylated	68439-46-3	surfactant
diethyl phthalate	84-66-2	fragrance	CDC 4th National Exposure Report CECBP - Priority Chemicals CWA 303(c) CWA 303(d)
diethyl phthalate	84-66-2	fragrance	Nonfunctional constituents
sodium hydroxide	1310-73-2	pH adjusting agent	OEHHA RELs
trisodium nitrilotriacetate, anhydrous	5064-31-3	chelate / se- questrant
Coumarin	91-64-5	fragrance	EU Fragrance Allergens

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Version number: GHS 1.0

Date of compilation: 2023-02-23

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

- Toxic or Hazardous Substance List (MA-TURA)

- Hazardous Substances List (MN-ERTK)

Legend

Name of substance	CAS No	DEP CODE	PBT / HHS / LHS	PBT / HHS Threshol d	De Minimis Con- centration Threshold
2-butoxy-1-ethanol		1022			1.0 %
sodium dodecylbenzenesulfonate	25155-30-0				1.0 %

Name of substance	CAS No	References	Remarks
2-butoxy-1-ethanol	111-76-2	A, O	skin

A American Conference of Governmental Industrial Hygienists (ACGIH), "Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices for 1992-93", available from ACGIH

O Occupational Safety and Health Administration (OSHA), Safety and Health Standards, Code of Federal Regulations, title 29, part 1910, subpart Z, "Toxic and Hazardous Substances, 1990." General information: Minnesota Department of Labor and Industry, Occupational Safety and Health Division

skin If a potential for absorption from skin contact merits special consideration, the word "skin" follows the substance name. - Hazardous Substance List (NJ-RTK)

Legend

CA Carcinogenic
F2 Flammable - Second Degree

- Hazardous Substance List (Chapter 323) (PA-RTK)

Legend
E Environmental hazard

- Hazardous Substance List (RI-RTK)

Legend
T Toxicity (ACGIH®)

California Environmental Protection Agency (Cal/EPA): Proposition 65 - Safe Drinking Water and Toxic Enforcement Act of 1987

none of the ingredients are listed

VOC content

Name of substance	CAS No	Remarks	Classifications
2-butoxy-1-ethanol	111-76-2		CA F2
sodium dodecylbenzenesulfonate	25155-30-0

Name acc. to inventory	CAS No	Classification
ETHANOL, 2-BUTOXY-	111-76-2
BENZENESULFONIC ACID, DODECYL-, SO- DIUM SALT	25155-30-0	E

Name of substance	CAS No	References
2-butoxy-1-ethanol	111-76-2	T

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

Version number: GHS 1.0

Date of compilation: 2023-02-23

- Regulated Volatile Organic Compounds (VOC-EPA)
- Regulated Volatile Organic Compounds (VOC-Cal ARB)

Industry or sector specific available guidance(s)

NPCA-HMIS® III

Hazardous Materials Identification System. American Coatings Association.

4.5 % 4.5 %

Category	Rating	Description
Chronic	*	chronic (long-term) health effects may result from repeated overexposure
Health	2	temporary or minor injury may occur
Flammability	2	material that must be moderately heated or exposed to relatively high ambient temperat- ures before ignition can occur
Physical hazard	0	material that is normally stable, even under fire conditions, and will not react with water, polymerize, decompose, condense, or self-react. Non-explosive
Personal protection	-

Chronic: Flammability: Health:
Personal protection: Physical hazard:

NFPA® 704

chronic hazard
flammability hazards
health hazard
personal protective equipment (PPE) for normal use reactivity

National Fire Protection Association: Standard System for the Identification of the Hazards of Materials for Emergency Re- sponse (United States).

Category	Degree of hazard	Description
Flammability	2	material that must be moderately heated or exposed to relatively high ambient temperat- ures before ignition can occur
Health	2	material that, under emergency conditions, can cause temporary incapacitation or residual injury
Instability	0	material that is normally stable, even under fire conditions
Special hazard

National inventories

Country	Inventory	Status
CA	DSL	all ingredients are listed
US	TSCA	all ingredients are listed as "ACTIVE"
EU	REACH Reg.	not all ingredients are listed
AU	AIIC	all ingredients are listed
CN	IECSC	not all ingredients are listed
EU	ECSI	not all ingredients are listed
JP	CSCL-ENCS	not all ingredients are listed
JP	ISHA-ENCS	not all ingredients are listed
KR	KECI	not all ingredients are listed

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Legend

AIIC
CICR CSCL-ENCS DSL
ECSI
IECSC INSQ ISHA-ENCS KECI
NZIoC PICCS REACH Reg. TCSI
TSCA

Date of compilation: 2023-02-23

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

Country	Inventory	Status
MX	INSQ	not all ingredients are listed
NZ	NZIoC	all ingredients are listed
PH	PICCS	not all ingredients are listed
TR	CICR	not all ingredients are listed
TW	TCSI	all ingredients are listed

Australian Inventory of Industrial Chemicals
Chemical Inventory and Control Regulation
List of Existing and New Chemical Substances (CSCL-ENCS)
Domestic Substances List (DSL)
EC Substance Inventory (EINECS, ELINCS, NLP)
Inventory of Existing Chemical Substances Produced or Imported in China National Inventory of Chemical Substances
Inventory of Existing and New Chemical Substances (ISHA-ENCS)
Korea Existing Chemicals Inventory
New Zealand Inventory of Chemicals
Philippine Inventory of Chemicals and Chemical Substances (PICCS) REACH registered substances
Taiwan Chemical Substance Inventory
Toxic Substance Control Act

15.2 Chemical Safety Assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information, including date of preparation or last revision

Indication of changes (revised safety data sheet)

Alignment to regulation: Globally Harmonized System of Classification and Labelling of Chemicals ("Purple book"). Restructuring: section 9, section 14

Abbreviations and acronyms

Abbr.	Descriptions of used abbreviations
29 CFR 1910.1000	29 CFR 1910.1000, Tables Z-1, Z-2, Z-3 - Occupational Safety and Health Standards: Toxic and Hazardous Sub- stances (permissible exposure limits)
49 CFR US DOT	49 CFR U.S. Department of Transportation
ACGIH®	American Conference of Governmental Industrial Hygienists
ACGIH® 2019	From ACGIH®, 2019 TLVs® and BEIs® Book. Copyright 2019. Reprinted with permission. Information on the proper use of the TLVs® and BEIs®: http://www.acgih.org/tlv-bei-guidelines/policies-procedures-presentations/tlv- bei-position-statement
Acute Tox.	Acute toxicity
Asp. Tox.	Aspiration hazard
ATE	Acute Toxicity Estimate
Cal/OSHA PEL	California Division of Occupational Safety and Health (Cal/OSHA): Permissible Exposure Limits (PELs)
Cal ARB	California Air Resources Board
CAS	Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
Ceiling-C	Ceiling value
DEP CODE	Department of Environmental Protection Code

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Abbr.

DGR DNEL EC50

EINECS EL50

ELINCS EPA

ErC50

Eye Dam. Eye Irrit. Flam. Liq. GHS HHS IARC IATA IATA/DGR ICAO IMDG LC50

LHS
LL50 NIOSH REL NLP NPCA-HMIS® III OSHA
PBT
PEL PNEC
ppm
Skin Corr. Skin Irrit. Skin Sens. STEL

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

Descriptions of used abbreviations

Dangerous Goods Regulations (see IATA/DGR) Derived No-Effect Level

Date of compilation: 2023-02-23

Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing 50 % changes in response (e.g. on growth) during a specified time interval

European Inventory of Existing Commercial Chemical Substances

Effective Loading 50 %: the EL50 corresponds to the loading rate required to produce a response in 50% of the test organisms

European List of Notified Chemical Substances

Environmental Protection Agency. An agency of the federal government of the United States charged with protect- ing human health and the environment

≡ EC50: in this method, that concentration of test substance which results in a 50 % reduction in either growth (EbC50) or growth rate (ErC50) relative to the control

Seriously damaging to the eye
Irritant to the eye
Flammable liquid
"Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations Higher hazard substance
International Agency for Research on Cancer
International Air Transport Association
Dangerous Goods Regulations (DGR) for the air transport (IATA)
International Civil Aviation Organization
International Maritime Dangerous Goods Code
Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing 50 % lethal-

ity during a specified time interval
Lower hazard substance
Lethal Loading 50 %: the LL50 corresponds to the loading rate causing 50 % lethality
National Institute for Occupational Safety and Health (NIOSH): Recommended Exposure Limits (RELs) No-Longer Polymer
National Paint and Coatings Association: Hazardous Materials Identification System - HMIS® III, Third Edition Occupational Safety and Health Administration (United States)
Persistent, Bioaccumulative and Toxic
Permissible exposure limit
Predicted No-Effect Concentration
Parts per million
Corrosive to skin
Irritant to skin
Skin sensitization
Short-term exposure limit

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Version number: GHS 1.0

Date of compilation: 2023-02-23

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Degreaser

Abbr.	Descriptions of used abbreviations
STOT SE	Specific target organ toxicity - single exposure
TLV®	Threshold Limit Values
TWA	Time-weighted average
VOC	Volatile Organic Compounds
vPvB	Very Persistent and very Bioaccumulative

Key literature references and sources for data

OSHA Hazard Communication Standard (HCS), 29 CFR 1910.1200.

Transport of dangerous goods by road or rail (49 CFR US DOT). International Maritime Dangerous Goods Code (IMDG). Dan- gerous Goods Regulations (DGR) for the air transport (IATA).

Classification procedure

Physical and chemical properties: The classification is based on tested mixture.
Health hazards, Environmental hazards: The method for classification of the mixture is based on ingredients of the mixture (ad- ditivity formula).

List of relevant phrases (code and full text as stated in section 2 and 3)

Code	Text
H226	Flammable liquid and vapor.
H227	Combustible liquid.
H302	Harmful if swallowed.
H304	May be fatal if swallowed and enters airways.
H312	Harmful in contact with skin.
H314	Causes severe skin burns and eye damage.
H315	Causes skin irritation.
H317	May cause an allergic skin reaction.
H319	Causes serious eye irritation.
H330	Fatal if inhaled.
H331	Toxic if inhaled.
H332	Harmful if inhaled.
H335	May cause respiratory irritation.

Disclaimer

This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for this product.

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